What sort of a house are you in?
Current heat pumps put out low temperatures (about 45°) so you need larger radiators than the gas/oil boilers as the water temperature is lower so the emitter needs more surface area. If you currently have single rads a simple swap over to double doubles (two emiters with two waffles between may work. Better yet would be wet underfloor heating, you get a much better spread of heat (I had electric U/F heating until it got too expensive to run) and it is just better as all of your walls become useful. Downside you'll have to break out the existing screed or lift the existing floor boards, either way a lot of work and money.
Due to the lower temperature and lower power of the heat pumps you have to leave them running 24/7 ideally at a constant temperature as they don't have the grunt to boost the temperature in your house quickly.
The M&E engineer who did a heat pump seminar at work for us said it also has to be carefully designed and picked for your house as a too-weak heat pump is as bad as a too-powerful heat pump. This engineer said he didn't think heat pumps were the right choice for much of the existing housing stock. The Scandinavians bolster their heat pump heating with log burners which due to clean air laws, lack of chimneys and terraces/apartments isn't always practical in the UK.
Also if you are planning an extension you'd be better off waiting until that is done or you'll wind up getting hit for a new heat pump as well as build costs.
How good are your windows? Air leakage is an absolute killer for low-temperature systems/efficiency. I replaced the knackered old first-generation double glazing that was nearly as old as me (interestingly only one pane had blown) with triple-glazed UPVC windows, FYI it was a £40 uplift over double glazed. Even with the trickle vents, the improvement is vast. It was cooler upstairs with the 40° day we had last year than the 30° days we had the year before.
You may need to to insulate the walls and loft as heat out needs replacing.
Could do more but have to work.