ACC is very good on any modern car. Where you have to be careful is to trust the car to brake hard when it needs to and not be tempted to half intervene. I have let the car do almost an emergency brake from 68mph on the motorway and it really was scary to trust it - but it worked. The worst time is to have the car accelerating to the set speed, the car in front has stopped and it is just out of sight of the detection system, especially if you have it set to one space rather than three. So you are accelerating when you can see the traffic is stationary ahead, the key is not to tap the brakes in fear- then the ACC system is disengaged, it is almost fatalistic driving. You either have to trust it or never trust it. But using ACC on the M25 is pure joy, stop,start, crawl, speed up, slow down - just so relaxing.
Having re-read this, I would not rely on the car stopping itself, it is too scary and if it did fail you are going to have a bad accident. ACC is good for cruising on the motorway and stop and starts in traffic, but approaching stationary cars and relying on it when you are travelling at speed is too risky. It was white knuckles when I did it once and I do not know why I trusted it, I would not advise relying on it with hindsight and I would not do anything that reckless again!