It just doesn't work like that!You could set hours during which you would be guaranteed not to get slots from Octopus, so you wouldn't need to manually switch it off. (This was suggestion #5).
Edit: In case I didn't make this clear enough, it would work as follows:
You'd be able to set multiple hour ranges up in the IOG app that would restrict the hours you'd be offered charging slots.
If you have solar, and your main production is (say) 8am-6pm, you could set IOG to never give you a charging slot during that time. Or whatever you need not to interfere with your solar configuration.
If you have a home battery, which you charge at night on the low rate between 11.30pm-1.30am (for example), you could set IOG to only give you charging slots between 1.30am and (say) 7.30am. Then you set your battery not to discharge during those hours.