Ok, day 2 update:
Yesterday evening, with 100w draw on the V2L, the battery voltage started slowly dropping as the evening went on. We noticed that the car was doing a pulse style charging, every now and again, seemingly at random, the voltage would momentarily spike to 14.3 ish volts then drop back down. That then seemed to stop and the voltage slowly dropped down to below 13v. I decided to put the car in the on position until bedtime, and duly the battery was held at 14.1v until I switched it off again.
This morning, a 2% drop in HV battery level and the main 12v battery showing 12.2v on the app - unfortunately I didn’t get a chance to put the multimeter on the battery to confirm this. Given that the battery spend at least 12 hours on charge yesterday, 12.2v tells me either there was a load on it again overnight and/or the battery is knackered.
More likely the latter, as on putting the car in ready mode, the voltage dropped to 10.2v and the car threw up lots of error messages, intermittently shutting off and reconnecting the HV battery. Eventually it settled itself down and is currently sitting in ready mode with the 12v battery charging as you would expect.
Two things come to mind: quite clearly the 12v battery is not as healthy as you would expect a new battery (as discussed above, we know why that could be). Secondly and in my mind more annoyingly, is that the car doesn’t seem to be able to recognise a discharging 12v battery in off mode (not for an extended period anyhow) and will quite happily let it discharge to the point of not staring the car, even though it has the means to correct it.
In summary, it seems there is a load on the 12v battery with the car off and V2L attached (even with no AC devices attached). The car will pulse charge for a while but will ultimately allow this to discharge the battery to the point of needing a jump start