It follows then that this confusion may be simply to the fact that MG have decided (presumably to keep documentation update costs down) to have a common 'one manual' for all battery / model variants of the MG4 and the statement I picked out may be referring to the SE LFP battery - thus ignoring the higher mileage NMC battery requirement?
That's what I was thinking. What you quoted sounded like a bit of a mish-mash of the two battery types. They really ought to be more clear about it.
At first, I believe, you could set the 80% charging limit on the app for all cars. Then by the time I got my car, although it looked as if you could do that, in practice the SR ignored the limit and went right on to 100% regardless. Confused the life out of me, because I'd been reading so much about charging to 80% (although my dealer said no, charge to 100%). At the last revision the ability to set a charging limit disappeared entirely for the SR.
MG are clearly pushing SR owners to charge to 100% whenever the car is left on its own to charge.
With the LFP battery, the MG recommendation is a 100% charge once a week, not every time you charge it. It is fine being charged to other levels so long as once a week you do a 100% charge.
For NMC it recommends 100% once a month, but no problem doing it more often than that as needed for long distance.
Fears about the effects of overcharging on range and degradation are often overblown, so it is not something I worry about, I just use the car as I need to.
If you are keeping it for 10 years or doing a taxi mileage, these things will make a difference, but otherwise life is too short.
The way it seems to work with the LFP is that you can't set the app to cut its charge short. Unless you physically intervene, it will get to 100% and balance. If you're on an AC charger there's really no point in doing anything else unless you need to get on your way sooner.
If you're on a DC charger you're probably going to stop the charge short of 100% for all the usual reasons anyway. (The day I left mine on a DC charger because reasons, it actually stopped by itself at 98%.)
So there are going to be occasions when, even with the LFP, you're not going to charge to 100%. Either you're on a DC charger, or you need to interrupt an AC charge to get going. If you're doing much of that, you have to remember to let the car get to 100% and balance at least once a week. But if you let it do its own thing, it will go to 100% and balance every time you charge.