If oxygen were 21% of the air we breath, we'd have a lot more energy and ICE vehicle would operate more efficiently ...... You need to be in a forest or sealed green house to get better than 19% oxygen and 78% nitrogen and the rest made up "other gasses"
If the tyre is deflate to equal the pressure outside the tyre, our pressure testing equipment would read 0 psi, but it would actually be 1 bar (14.7psi) at sea level. To achieve 30 psi, the actual pressure would be 3 bar.
Using 19% as the 1 bar pressure oxygen capacity, then another 2 bar of nitrogen, only roughly 6% of the total gas contained inside the tyre is oxygen ..... this will rapidly oxidise with the rubber of the tyre and make its way out through the sidewalls, then next pressure top up with nitrogen will reduce that 6% even further ...... It does work .....
T1 Terry